High photocatalytic activity in nitrate reduction by using Pt/ZnO nanoparticles in the presence of formic acid as hole scavenger
نویسندگان
چکیده
In this work, the photocatalytic reduction of nitrate in water was examined using zinc oxide loaded with platinum nanoparticles and formic acid as a hole scavenger (electron donor). The data obtained in the structural characterization and in the nitrate photoreduction experiments showed that 1wt% Pt/ZnO photocatalyst had the highest photocatalytic activity and selectivity toward nitrogen. Selectivity and conversion were higher than 98 and 70%, respectively. This system effectively promoted the photocatalytic reduction of NO3 to N2. Nitrite ions were not observed during the reaction and a negligible amount of ammonia was formed.
منابع مشابه
Ag/Pt Core-Shell Nanoparticles on Graphene Nanocomposite for Effective Anodic Fuels Electro-oxidation
The nanocomposite consists of the Ag as a core and Pt as shell on the surface of graphene nanosheets (Ag/Pt-G) was synthesized with a simple method and used as a novel electrochemical platform for an efficient catalyst for oxidation of the ethanol, methanol and formic acid. The morphology and electrochemical properties of Ag/Pt-G nanocomposite were investigated by TEM, X-ray diffraction, and vo...
متن کاملEnhancement of photocatalytic activity of ZnO–SiO2 by nano-sized Pt for efficient removal of dyes from wastewater effluents
In this work, ZnO/SiO2 nanoparticles were prepared using sol-gel method, and platinum particles were loaded on ZnO/SiO2 nanoparticles by photoreductive method. Samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FT-IR). The XRD patterns showed that the zinc oxide samples have a wurtzite structure (hexagonal phase...
متن کاملEnhancement of photocatalytic activity of ZnO–SiO2 by nano-sized Pt for efficient removal of dyes from wastewater effluents
In this work, ZnO/SiO2 nanoparticles were prepared using sol-gel method, and platinum particles were loaded on ZnO/SiO2 nanoparticles by photoreductive method. Samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FT-IR). The XRD patterns showed that the zinc oxide samples have a wurtzite structure (hexagonal phase...
متن کاملOptimization of Cr(VI) Photocatalytic Reduction by UV/TiO2 : Influence of Inorganic and Organic species and Kinetic Study
Background & Aims of the Study: Chromium is widely detected in surface waters and underground waters, which usually appear as Cr(VI), and Cr(III), at sites associated with industrial activities. Cr(VI), in effluent streams with a high level of mobility and notorious mutagenic and carcinogenic toxicity; thus Cr(III) does not have much mobility in soil. So, converting it into less h...
متن کاملComparison of Photocatalytic Activities of Two Different Dyes Using Pt-Modified TiO2 Nanoparticles under Visible Light
The photocatalytic degradation of Acid Red 91 (AR91) and Acid Yellow 23 (AY23) with different molecular structures and different substitute groups using Pt modified TiO2 (PtTiO2 ) nanoparticles was investigated in the presence of visible light irradiation. Pt-TiO2 nanoparticles were prepared with photodiposition method (PD) and characterized by X-ray diffraction (XRD), scanning electron microgr...
متن کامل